CoffeeBox suggests using spare brewed coffee in brownies and stews rather than discarding every unused portion. The appealing connection is flavor: roasted, bitter and chocolate-like impressions can add depth to foods that already share those associations. More coffee is not automatically better, and an unpleasant brew can introduce the same problem into a recipe.
Use a small amount in a recipe designed to accommodate liquid, accounting for the coffee within the total rather than adding an arbitrary extra cup. In a chocolate dessert it can support cocoa character; in a savory sauce it may add darkness and bitterness. Taste carefully where the recipe permits, and avoid claiming that a little coffee reliably breaks down meat or reproduces the effect of slow cooking.
Keep food handling separate from waste reduction. Reserve clean coffee before drinking from the serving vessel, cool and store it appropriately, and follow the finished recipe's storage guidance. Milk-containing leftovers require particular care. Coffee is an ingredient, not a preservation method, and reheating does not make every poorly stored leftover suitable for cooking. A fresh small brew is often the simplest option when storage history is uncertain.

The conversation
A good question can make a better brew.